History
As long as 80 years ago it was
recognized that hydrocyanic acid could be useful in pest control
but it took half this time to popularize the method.
Deficiencies and disadvantages
had first of all to be eliminated from the method of application.
First this had been done in such a way that hydrocyanic acid was
no more developed on the spot by mixing cyanides and acid, but
this process already took place in the factory: The so-called
"pot method" was replaced by liquid hydrocyanic acid. The few
deficiencies of this procedure were removed in the early twenties
by the ZYKLON method: One added liquid HCN to a "carrier
substance", thus simplifying handling whilst all favourable
properties of liquid HCN were maintained. At the same time,
danger to the operator was reduced to a minimum. Hydrocyanic acid
in the form of ZYKLON can be safely stored for considerable
periods and under all climatic conditions, any quantity of gas
can be easily measured, quickly and cleanly released. Any
residures are completely harmless.
Composition
In ZYKLON pure (98%-99%)
liquid hydrocyanic acid is chemically stabilized and absorbed in
a porous, inert material. It is supplied in snippets or discs
prepared from wood pulp. Snippets generally are preferred as in
view of their larger surface they give off the gas more rapidly.
Upon request also discs can be supplied. The aborbent material
can easily be collected at the end of the fumigation.
Packing
ZYKLON is packed in handy,
gas-tight tins of various sizes which are packed in strong wooden
cases. One case, measuring 72 x 50 x 36 cm contains:
Imperial - units 16 tins, each
containing 40 ozs. HCN - total 40 lbs HCN or 30 tins, each
containing 16 ozs. HCN - total 30 lbs HCN.
Toxicity
No thoroughly effective
pesticide is known to exist which could be considered to be
harmless to human beings or mammals. Fatal concentrations of HCN
impede or completely cut off the oxygen supply to the cells. The
poison can enter the body in three ways: through the mouth, the
respiratory organs, or the pores of the skin. The latter will
occur in particular if the body is exposed to high concentration
for any length of time and in unfavourable conditions (great
heat).
Methods
Prior to fumigation, the tins
must be distributed about the building. The tins are opened, and
the ZYKLON is scattered so as to reach even the remotest parts of
the building. If this is done correctly the gas will develop
evenly and instantaneously throughout the premises. Spaces
difficult to reach may be charged separately. In multi-storied
buildings one begins with the top floor, and then works towards
the exit, taking care that nobody re-enters rooms already
charged. Even under mask protection it is not advisable to expose
oneself to the gas more than is absolutely necessary. The exit
door is sealed after everybody has left the building; warning
notices must be put up before gassing commences and a guard
placed near the building to prevent unauthorised persons from
entering. Time of exposure depends on the type of pests to be
attacked; for the destruction of the various types of moths and
their pre-adult stages 24 hours will suffice, against other kinds
of insect pests one should fumigate for 48 hours. If there are
any dense stowages or bulkss of commodities to penetrate, the
time of exposure may need to be extended to 72 hours.
Ventilation
During this operation
gas-masks must be worn. The ventilation takes place in the
reverse direction to the gassing. All windows near the entrance
are opened first, then gradually those in the rest of the
building. It is advisable to work only for 10 to 15 minutes at a
time and then to make interruptions of half an hour, as a
precaution against skin poisoning.
Depending on concentration,
outdoor tempature and weather conditions, ventilation will take
at least 10 hours. Clearing of tins and residues may be commenced
before the end of airing. Windows and doors must remain open, and
gas-masks kept available. ZYKLON tins and absorbent material must
always be collected and cleared away before the resumption of
work.